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Subscriber access provided by Chicago State University ACS Applied Materials & Interfaces is published by the American Chemical Society.1155 Sixteenth Street N.W., Washington, DC 20036Published by American Chemical Society. Copyright © American Chemical Society.However, no copyright claim is made to srcinal U.S. Government works, or worksproduced by employees of any Commonwealth realm Crown government in the courseof their duties. Article Tribochemistry of Bismuth and Bismuth Salts for Solid Lubrication Pablo Gonzalez Rodriguez, Karin van den Nieuwenhuijzen,Walter Lette, Dik Schipper, and Johan E. ten Elshof ACS Appl. Mater. Interfaces , Just Accepted Manuscript ã DOI: 10.1021/acsami.6b02541 ã Publication Date (Web): 03 Mar 2016 Downloaded from http://pubs.acs.org on March 3, 2016 Just Accepted “Just Accepted” manuscripts have been peer-reviewed and accepted for publication. They are postedonline prior to technical editing, formatting for publication and author proofing. The American ChemicalSociety provides “Just Accepted” as a free service to the research community to expedite thedissemination of scientific material as soon as possible after acceptance. “Just Accepted” manuscriptsappear in full in PDF format accompanied by an HTML abstract. “Just Accepted” manuscripts have beenfully peer reviewed, but should not be considered the official version of record. They are accessible to allreaders and citable by the Digital Object Identifier (DOI®). “Just Accepted” is an optional service offeredto authors. Therefore, the “Just Accepted” Web site may not include all articles that will be publishedin the journal. After a manuscript is technically edited and formatted, it will be removed from the “JustAccepted” Web site and published as an ASAP article. Note that technical editing may introduce minorchanges to the manuscript text and/or graphics which could affect content, and all legal disclaimersand ethical guidelines that apply to the journal pertain. ACS cannot be held responsible for errorsor consequences arising from the use of information contained in these “Just Accepted” manuscripts. 1 P. GR 12 , K.J.H. N 2 , W. L 3 , D.J. S 3 , J.E. E 2,* 1 M (M2). E 25, 2628 XG D, N. 2 I M S, MESA+ I N, U T, P.O. B 217, 7500 AE E, T N. 3 S T T, F E T, U T, P.O. B 217, 7500 AE E, T N O . S . T , (B 2 S 3 ), (B 2 (SO 4 ) 3 ) (B 2 O 3 ) 580 C. T , . T ( µ ≈ 0.08) 200 C. A 271 C, . B . B µ ≈ 0.15 500 C, , . A X (XRD), , (HRSEM) X (EDS). T , . : , , , , , , , S , . A Page 1 of 20ACS Paragon Plus EnvironmentACS Applied Materials & Interfaces 123456789101112131415161718192021222324252627282930313233343536373839404142434445464748495051525354555657585960 2 , , 1,2 . M , , 3 , 4 5 . 6 I , , (T TM ). 7,8 N, , , , , . 9 B 10 . 1113 T . B , , . 14 T , . 15 D , . B . 16 I , . 17,18 O . T . B (B 2 S 3 ) , . 19 B , B 2 S 3 . H, , .. , . 9 P . 20 A . T, . B , 21,22 23 , 5 . E . B . 24 T, . B Page 2 of 20ACS Paragon Plus EnvironmentACS Applied Materials & Interfaces 123456789101112131415161718192021222324252627282930313233343536373839404142434445464748495051525354555657585960 3 . . B (B, ABCR, 99.9 %), (III) (B 2 S 3 , ABCR, 99.9 %), (III) (B 2 O 3 , A A, 99 %) (III) (B 2 (SO 4 ) 3 , A A, 99 %) , . T 2 % . T ( φ = 1 ) 48 , . T 90 C. T, 200 µ L . . PD: T HT PD (PD) CSM . T . T PD , . I . T (10 , SKF). T 27 2 ( φ = 5.9 ), 75 µ / 2 ( 75 / 2 ). T 10 N, 370 P. T EN 10278 , , SC 2000 3 µ . T = 0.90 0.25 µ . T , 1 /. D + 25 580 C. T (CF) 5 . T Page 3 of 20ACS Paragon Plus EnvironmentACS Applied Materials & Interfaces 123456789101112131415161718192021222324252627282930313233343536373839404142434445464748495051525354555657585960
