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SAFETY DATA SHEET Version: 6.0Effective date: 12/03/2012Previous Date: 23/12/2009 CORRSHIELD NT4292 Section 1: Identification of the substance/mixture and of the company/undertaking Product identifierCORRSHIELD NT4292Version number 6.0 Revision date 12/03/2012 Supersedes date 23/12/2009 Relevant identified uses of the substance or mixture and uses advised againstIdentified uses Corrosion inhibitor Uses advised against None known.GE Water & Process Technologies BVBAToekomstlaan 54Industriepark Wolfstee2200 HERENTALStel : +32 14 / 25 91 11fax : +32 14 / 25 91 12e-mail :
[email protected] Emergency telephone number Multilingual emergency number (24/7)Europe, Middle East, Africa, Israel (Europe and Englishlanguage speaking countries):+44(0)1235 239670Middle East & Africa (speaking Arabic):+44(0)1235 239671 Official advisory body :ANTIGIFCENTRUMBruynstraat 1B-1120 BRUSSEL+ 32 70 245 245 Details of the supplier of the safety data sheet Section 2: Hazards identification Classification of the substance or mixtureClassification according to Directive 67/548/EEC or 1999/45/EC as amendedClassification O;R8, T;R25, N;R50 Hazard summaryPhysical hazards Contact with combustible material may cause fire. Health hazards Toxic if swallowed. Environmental hazards Very toxic to aquatic organisms. Label elementsLabel according to Directive 67/548/EEC or 1999/45/EC as amendedContains: Sodium nitrite Material name: CORRSHIELD NT4292 Page: 1 / 9 SAFETY DATA SHEET Version: 6.0Effective date: 12/03/2012Previous Date: 23/12/2009 CORRSHIELD NT4292 ToxicOxidisingDangerous for theenvironment R-phrases R25 Toxic if swallowed.R8 Contact with combustible material may cause fire.R50 Very toxic to aquatic organisms. S-phrases S36/37/39 Wear suitable protective clothing, gloves and eye/face protection.S45 In case of accident or if you feel unwell, seek medical advice immediately (show label wherepossible).S61 Avoid release to the environment. Refer to special instructions/safety data sheets. Supplemental label information Not applicable. Other hazards Not assigned. Section 3: Composition/information on ingredients MixturesChemical description Sodium nitrite, aqueous solution Chemical nameNotesINDEX No.REACH Registration No.CAS-No. / EC No.%Classification:DSD: O;R8, T;R25, N;R50Ox. Sol. 3;H272, Acute Tox. 3;H301, Aquatic Acute 1;H400 CLP: 007-010-00-401-2119471836-277632-00-0231-555-9>= 25Sodium nitriteThe classification of the above substance(s) is given, including the symbol letters and R phrases which are assigned in accordance with theirphysicochemical, health and environmental hazards. Please refer to section 16 (Relevant R phrases, used in sections 2 and 3 of this SDS),where the full text of each relevant R phrase is listed. Section 4: First aid measures Description of first aid measuresInhalation Remove to fresh air. Skin contact Wash with water. Eye contact Flush immediately with plenty of running water. Ingestion First rinse mouth with water.Immediately give 1-2 glasses of water, if victim is fully conscious.Do NOT induce vomiting!Seek medical attention. Most important symptoms andeffects, both acute and delayed Not available. Indication of any immediatemedical attention and specialtreatment needed Not available. Section 5: Firefighting measures Extinguishing mediaSuitable extinguishing media Flood with water.Use of CO2 or foam may not be effective. Unsuitable extinguishingmedia Not available. Material name: CORRSHIELD NT4292 Page: 2 / 9 SAFETY DATA SHEET Version: 6.0Effective date: 12/03/2012Previous Date: 23/12/2009 CORRSHIELD NT4292 Special hazards arising from thesubstance or mixture Oxides of nitrogen evolved in fire. Advice for firefightersSpecial protective equipmentfor firefighters Self contained breathing apparatus. (CEN : EN 137)Protective clothing (CEN : EN 469)Protective gloves (CEN : EN 659)Helmet (CEN : EN 443) Special firefightingprocedures Use standard firefighting procedures and consider the hazards of other involved materials.Prevent spillage and fire-fighting water from entering in public sewers or the immediate environment. Section 6: Accidental release measures Personal precautions, protective equipment and emergency proceduresFor non-emergencypersonnel Wear protective clothing, gloves and safety goggles. For emergency responders Use personal protection recommended in Section 8 of the MSDS. Environmental precautions Prevent from entering sewers or the immediate environment.Do not empty into drains, dispose of this material and its container to hazardous or special wastecollection point. Methods and material forcontainment and cleaning up Absorb onto inert material and dispose of according to Hazardous Waste Regulations. Reference to other sections Please refer also to section no. 8 'Exposure controls' for further information. Section 7: Handling and storage Precautions for safe handling Contains an oxidiser.Avoid all contact with reducing agents, oils, greases, organics and acids. Conditions for safe storage,including any incompatibilities Keep away from oxidisable and combustible materials.Store containers closed when not in use. Specific end use(s) Only for professional and industrial users Shelf life 720 days Section 8: Exposure controls/personal protection Control parametersOccupational exposure limits No exposure limits noted for the ingredient(s). Biological limit values No biological exposure limits noted for the ingredient(s). Recommended monitoringprocedures Not available. Exposure controlsAppropriate engineering controls Ensure good ventilation. Individual protection measures, such as personal protective equipmentEye/face protection Splash proof chemical goggles.CEN : EN 166 Skin protection- Hand protection Neoprene gloves (Protection against unintentional short-term contact)CEN : EN 374-1/2/3; EN 420 - Other Protective clothing.CEN : EN 340; EN 369; EN 465 Respiratory protection In case of insufficient ventilation, use a breathing mask with filter type: P2CEN : EN 140; EN 143; EN 149 Thermal hazards Not available. Material name: CORRSHIELD NT4292 Page: 3 / 9 SAFETY DATA SHEET Version: 6.0Effective date: 12/03/2012Previous Date: 23/12/2009 CORRSHIELD NT4292 Environmental exposure controls Prevent from entering in public sewers or the immediate environment.Do not empty into drains, dispose of this material and its container to hazardous or special wastecollection point. Section 9: Physical and chemical properties Information on basic physical and chemical propertiesAppearanceColour Yellow Physical state Liquid Odour Mild Odour threshold Not available. pH (concentrated product) 8,4 Melting point/freezing point < -20 °C Boiling point, initial boiling point,and boiling range 104 °C Flash point > 100 °C Pensky Martens (CC) Evaporation rate No information available. Flammability (solid, gas) Not available. Flammability limit - lower (%) Not available. Flammability limit - upper (%) Not available. Vapour pressure 18 Approximate (mmHg) at 21°C Vapour density < 1 (Air = 1) Relative density 1,29 Solubility (water) Completely soluble Partition coefficient(n-octanol/water) Not available. Auto-ignition temperature Not applicable. Decomposition temperature Not available. Viscosity No information available. Explosive properties Not applicable. Oxidizing properties Not applicable. Other dataShelf life 720 days Other information No relevant additional information available. Section 10: Stability and reactivity Reactivity Not available. Chemical stability Material is stable under normal conditions. Possibility of hazardous reactions Not applicable. Conditions to avoid No special requirement. Incompatible materials Avoid contact with strong reducing agents.Avoid contact with combustible materials.Do not mix with nitrosating agents (forms nitrosamines).Avoid contact with strong acids. Hazardous decompositionproducts Oxides of nitrogen evolved in fire. Material name: CORRSHIELD NT4292 Page: 4 / 9
